mireabulletinRussian Technological JournalRussian Technological Journal2782-32102500-316XRTU MIREA10.32362/2500-316X-2017-5-3-74-105mireabulletin-64Research ArticleК 70-ЛЕТИЮ МИРЭАTo the 70th anniversary of MIREAКОМПОЗИЦИОННЫЕ ПОЛИМЕРНЫЕ СУСПЕНЗИИ СО СЛОЖНОЙ МОРФОЛОГИЕЙ ЧАСТИЦCOMPOSITE POLYMER SUSPENSIONS WITH COMPLEX PARTICLE MORPHOLOGYПрокоповН. И.ProkopovN. I.prokopov@mitht.ruГрицковаИ. А.GritskovaI. A.noemail@neicon.ruГервальдА. Ю.GervaldA. Yu.noemail@neicon.ruБалашовМ. С.BalashovM. S.noemail@neicon.ruМосковский технологический университет (Институт тонких химических технологий)РоссияMoscow Technological University (Institute of Fine Chemical Technologies)Russian Federation2017280620175374105Copyright © Прокопов Н.И., Грицкова И.А., Гервальд А.Ю., Балашов М.С., 20172017Прокопов Н.И., Грицкова И.А., Гервальд А.Ю., Балашов М.С.Prokopov N.I., Gritskova I.A., Gervald A.Y., Balashov M.S.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://www.rtj-mirea.ru/jour/article/view/64

В настоящем обзоре приведена классификация полимерных частиц различного состава со сложной морфологией. Рассмотрены методы из изучения. Обобщены и проанализированы методы гетерофазной полимеризации, использующиеся для синтеза композиционных полимерных частиц с различной морфологией. Выявлены факторы, оказывающие влияние на свойства полимерных частиц.

The review is dedicated to the synthesis of composite polymer suspensions with complex particle morphology. Authors attempted to summarize effects of polymerization conditions on particle morphology. The significance of further investigations in the field of composite polymer suspensions synthesis was shown. The main aspects of different monomers emulsion homopolymerization, affecting the polymer particle morphology, such as polymerization topochemistry, free energy of particle formation, the kind of monomer and others were discussed. The determination methods of polymer particles phase structure may be shown to be classified as direct and indirect. The most frequently used investigation methods of suspension particles morphology viz electron microscopy, soap titration technique and film forming were described. General techniques of composite polymer particle synthesis, such as emulsion copolymerization and seed polymerization, were given and considered in detail. Advantages and disadvantages of each method were listed. Determination of particle morphology, using thermodynamic approach, was discussed. Obtained composite polymer particles were found to be classified into two large groups: non-uniform composite gradient particles and heterophase particles.

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